What Is Pyrite (Fool's Gold)? - Properties, Definition & Facts
The last thing you want is to be considered a fool the next time you go gold-panning. So to avoid that terrible fate, read this lesson and learn what the common mineral pyrite looks like.
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Fool's Gold is an expression used to describe the mineral pyrite (sometimes called iron pyrite). The name is derived from the old mining days, when (apparently) many novice gold prospectors mistook tiny pieces of the mineral for gold in their pans. Strangely enough, the mineral really looks nothing like gold. And I suppose that's why they were considered fools.
Pyrite is a metallic mineral that is composed of iron and sulfur atoms bound together in a ratio of 1:2 (FeS2), and it is arguably the most abundant sulfide mineral on Earth. The name comes from a Greek word for fire in reference to the tendency of the mineral to spark when struck against steel (in fact, it was used for that purpose in early flintlock rifles).
The mineral is found in many sedimentary rocks, such as limestone, shale and coal, as well as in metamorphic rocks like schist. It is a very common mineral in ore deposits, where it is found along with other metal-containing minerals. And yet it is not mined for its iron (the metal is difficult to extract). In some rocks, usually shale, pyrite replaces shell material to form what are known as pyritized fossils.
Pyrite rates a hardness of H=5.5 on Moh's hardness scale, the scale used by geologists to describe a mineral's resistance to being scratched. (For comparison, quartz is H=6, diamond is H=10 and gold is H=2.5). It has a brassy yellow color, but it does not look as bright yellow as gold. If the mineral is ground into powder - a physical property known as the streak- the color appears greenish-black (powdered gold is still yellow in case you're wondering).
Pyrite crystallizes from iron and sulfur-bearing water solutions, sometimes heated, in which there is very little free oxygen (that's known as a reducing environment in chemistry). Bacteria may also be involved in some pyrite deposits, particularly in shale.
When the mineral forms crystals they can assume the geometric shapes of a cube (with six square faces), octahedron (eight triangular faces) or pyritohedron (twelve pentagonal faces), or even combinations of those shapes. It also can be massive, lacking any visible crystal forms, and occur as irregular grains spread out through a rock.
Whether in crystal or massive form, pyrite has a metallic luster. However, because the mineral does react chemically in air, it often has a dull or tarnished appearance.
Chemical Properties and Uses
Gold atoms can substitute for the iron atoms in pyrite's atomic structure, and some gold deposits do contain pyrite that contains several tenths of a percent gold in it. That likely is the source of the confusion between the two; however, it hardly makes pyrite as valuable as pure gold. Nickel also substitutes in the structure, forming a closely-related sulfide mineral called bravoite.
When pyrite-bearing rocks are exposed to the elements, the mineral reacts readily with oxygen and water to form new iron oxide and sulfate minerals, as well as sulfuric acid. That chemical reaction causes the acid mine drainage that is a common problem in mining regions (including metal and coal mines).
On the other hand, that same chemical reaction has been used in commercial-scale sulfuric acid production since the 15th century. The mineral is also used to make sulfur dioxide, which is used to bleach paper and in other industrial applications.
Some of you may own marcasite jewelry. It is actually pyrite that has been cut or faceted and polished. Just to confuse matters, the jewelry shares the name of another iron-sulfide mineral (similar to pyrite) that is not used for jewelry. Maybe Fool's marcasite is a better name?
Pyrite is the most common iron sulfide mineral on Earth and is found in shale, coal, limestone, schist and many deposits of metallic ores. Its association with gold ore and its superficially similar appearance led to its confusion with the precious metal, and thus the name 'Fool's gold.' It often forms brassy-yellow, cubic crystals that have a shiny metallic luster. It is not mined for its iron content but is used to make sulfuric acid and other chemicals. Naturally-weathered pyrite creates acid mine drainage.
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